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在密闭体系中700℃、压力高达3 GPa条件下进行褐煤加水的模拟实验,分析实验产物中的萜烷的变化规律,进而对高压高温下有机质演化进行研究.实验结果表明,相同压力条件下,温度升高有利于有机质的成熟演化;压力增加会抑制或延迟油气的生成和有机质成熟;五环三萜烷ββ生物构型转化为αβ地质构型所需能量比烯烃双键加氢饱和更高.高温超高压条件下,研究样品中C24四环萜烷存在4种同分异构体,含量由高到低依次包括10β(H)-降A-羽扇烷、10p(H)-降A-奥利烷、C24-17,21-断藿烷和10β(H)-降A-乌散烷.高碳数烷烃在地幔高压力条件下仍可以存在,这为认识超压盆地的油气资源与深层油气成藏及保存提供了新的思路. 相似文献
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黄山高速公路穿行于皖南山区,公路建设过程中,汤口互通A匝道高边坡产生了大范围变形,严重威胁已有构筑物和施工安全。为保证边坡稳定,成立“应急指挥小组”,建立快速反应机制,并采用工程地质测绘、勘探、监测等手段,快速查明边坡结构特征,分析边坡变形机理和稳定性,提出应急治理方案。分析表明,该边坡为层间软弱夹层[JP2]发育的砂泥岩互层型顺向边坡,地质历史上边坡曾发生滑移—弯曲变形,公路施工时对弯曲隆起部位岩体进行开挖,引起坡体产生快速变形,在降雨、开挖等条件下,边坡产生整体失稳的可能性极大。在分析边坡变形机制基础上,应用变形控制理论,确定对边坡采取桩锚结合、综合排水的应急治理措施,并根据变形特点提出了应急治理施工步骤。应急治理措施实施后,边坡变形得到了有效控制,稳定性达到了高速公路的安全要求 相似文献
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Effect of Bacillus mucilaginosus on weathering of phosphorite and a preliminary analysis of bacterial proteins 总被引:3,自引:0,他引:3
The authors investigated the effect of Bacillus mucilaginosus on weathering of phosphorite. Analysis of different proteins was of significance in exploring the molecular biological mechanism in the bacterial weathering process. The concrete methods are described as follows: Mineral powder was put into liquid culture medium and B. mucilaginosus was incubated in the medium. The control (group) had no mineral powder in the medium. The treatments and controls were cultured simultaneously under the same condition. In a few days, the supernatant was filtrated, the main cations (Ca^2+, Mg^2+, Na^+, Mn^2+, Al^3+, Fe^3+, K^+) were measured by ICP-OES, and the contents of water soluble phosphorus (Pws) and silicon (Siws) were determined by colorimetry. The residual solid was weighed on the filter paper, followed by digestion with concentrated HNO3. The concentrations of the main cations and Pws, Siws in the digest liquid were measured by using the method mentioned above. After the supernatant was centrifuged, the precipitation was used to analyze the protein differences between the treatment groups and the control groups by 2-dimentional gel electrophoresis (2-DE). The experimental results showed that apatite and quartz were partially weathered, but kaolinite was dissolved completely. The population of bacteria increased when mineral powder was added in the liquid medium. Software analysis and comparison of the 2-DE pictures of bacterial proteins revealed 1134 visible protein spots in the treatment group, and 729 visible protein spots in the control group. To compare the bacterial protein expression contents of the treatment group with those of the control group, there were 496 different protein spots, including 214 protein spots which indicated that the protein contents increased, 75 protein spots were indicative of a decrease, and 207 proteins were newly synthesized. It is proposed that the increased bacterial contents may be related to some protein expression and activation after the 相似文献
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